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A novel strategy to synthesize CoMoO4 nanotube as highly efficient oxygen evolution reaction electrocatalyst.

Authors :
Li, Yanqiang
Wang, Chao
Cui, Ming
Chen, Siru
Ma, Tingli
Source :
Catalysis Communications. Nov2019, Vol. 131, pN.PAG-N.PAG. 1p.
Publication Year :
2019

Abstract

Designing efficient oxygen evolution reaction (OER) electrocatalysts is crucial for practical applications in water splitting and metal-air battery devices. Special structures of materials often bring in unprecedented catalytic activity. Herein, we first report the synthesis of CoMoO 4 nanotube by using MoO 3 @ZIF-67 nanorod. The CoMoO 4 nanotube shows high OER activity with a low overpotential of 315 mV delivering a current density of 10 mA cm−2. The electro-catalytic activity surpasses that of many Co and Mo-based catalysts. Furthermore, the strategy presented here is facile, and can be extended to the synthesis of other Mo-based nanotube materials for energy storage and conversion. Unlabelled Image • CoMoO 4 nanotube was prepared by using MOF composite as precursor for the first time. • The CoMoO 4 shows high a specific surface area of 157 m2 g−1. • The CoMoO 4 shows high OER activity of 10 mA cm−2 at an overpotential of 315 mV. • The CoMoO 4 also shows outstanding long-term electrochemical durability. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15667367
Volume :
131
Database :
Academic Search Index
Journal :
Catalysis Communications
Publication Type :
Academic Journal
Accession number :
138499867
Full Text :
https://doi.org/10.1016/j.catcom.2019.105800