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One-step electrodeposition synthesis of high performance carbon nanotubes/graphene-doped Ni(OH)2 thin film electrode for high-performance supercapacitor.
- Source :
-
Electrochimica Acta . Nov2019, Vol. 322, pN.PAG-N.PAG. 1p. - Publication Year :
- 2019
-
Abstract
- In this work, we successfully synthesized Ni(OH) 2 thin film electrode in situ doped with CNTs/rGO by cathodic electrodeposition on titanium mesh. The doping effects of CNTs and/or rGO, and the technical conditions, are investigated. The doping of CNTs/rGO can greatly improve the electrochemical performance by forming the porous structure and the conductive network in the Ni(OH) 2 thin film. The highest capacity, 429.5 mAh/g at a current density of 5 A/g, is achieved for the electrode with 0.24 mg/cm2 Ni(OH) 2 and codoped with CNTs and rGO, as compared with only 323.9 mAh/g for undoped electrode. Even at 100 A/g, the specific capacity can still remain 347.5 mAh/g (vs. 221.5 mAh/g for the undoped electrode), and after 1000 cycles, the retention rate of the specific capacity is 74.9% as compared with only 42.7% for the undoped electrode. Even with higher loading amounts of 1.92 mg/cm2 Ni(OH) 2 , the specific capacity retention rate of the codoped electrode is still much higher than that of the undoped electrode. The high electrochemical performance can be attributed to the better ion/electron transfer ability of the codoped electrode. In conclusion, by the cathodic electrodeposition and in situ doping of CNTs/rGO, the porous structure and the conductive network in Ni(OH) 2 film can be constructed, which can improve the ion/electron transfer ability, therefore, the high performance film electrode with higher loading amount of Ni(OH) 2 can be prepared. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00134686
- Volume :
- 322
- Database :
- Academic Search Index
- Journal :
- Electrochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 138572335
- Full Text :
- https://doi.org/10.1016/j.electacta.2019.134747