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Ultrahigh sorption and reduction of Cr(VI) by two novel core-shell composites combined with Fe3O4 and MoS2.
- Source :
-
Journal of Hazardous Materials . Nov2019, Vol. 379, pN.PAG-N.PAG. 1p. - Publication Year :
- 2019
-
Abstract
- • Core-shell Fe 3 O 4 @MoS 2 and MoS 2 @Fe 3 O 4 composites were synthesized. • Both Fe 3 O 4 @MoS 2 and MoS 2 @Fe 3 O 4 showed high removal capability for Cr(VI). • Both Fe 3 O 4 @MoS 2 and MoS 2 @Fe 3 O 4 are superparamagnetic. • Fe 3 O 4 @MoS 2 and MoS 2 @Fe 3 O 4 are eco-friendly during the synthesis process and wastewater treatment. • Synergetic reduction makes F@M an outstanding material for Cr(VI) removal. In this investigation, two novel magnetic core-shell Fe 3 O 4 @MoS 2 (F@M) and MoS 2 @Fe 3 O 4 (M@F) composites were synthesized and exploited for Cr(VI) elimination. Eco-friendly preparation methods were applied for the synthesis of Fe 3 O 4 and MoS 2 composites. The experimental results showed that both F@M and M@F have high saturation magnetization values (43.2 emu/g for F@M and 49.9 emu/g for M@F), excellent maximum sorption capacities of Cr(VI) at pH 5.0 and 298 K (324.3 mg/g for F@M, 290.2 mg/g for M@F), remarkable Cr(VI) removal efficiencies (Cr(VI) sorption equilibrium by both F@M and M@F can be reached in 90 min) and nice regeneration properties (the sorption capabilities of F@M and M@F decreased slightly after five consecutive sorption/desorption cycles). Chemical reduction of Cr(VI) to Cr(III) occurred on the surface of F@M and M@F, and the synergetic reduction of sulfur and ferrous ions made F@M an outstanding material for Cr(VI) removal. This paper highlights F@M and M@F as potential, eco-friendly and ultrahigh-efficiency materials for Cr(VI) pollution cleanup. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03043894
- Volume :
- 379
- Database :
- Academic Search Index
- Journal :
- Journal of Hazardous Materials
- Publication Type :
- Academic Journal
- Accession number :
- 138651276
- Full Text :
- https://doi.org/10.1016/j.jhazmat.2019.120797