Efficient Synthesis of Sulfonyl Diphenylsulfides Catalyzed via Cu–MOF of PCN‐6'.

In this work, we used a metal organic framework of PCN‐6', which prepared from copper compound and iazine‐2,4,6‐triyl‐benzoate (H3TATB) ligand, to catalyze the disulfide reacted with aryl iodide and sulfonyl chloride to synthesize of sulfonyl diphenylsulfides. A series of sulfonyl diphenylsulfide derivatives were synthesized with medium or high yields. [ABSTRACT FROM AUTHOR]