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Enhanced magneto-electric coupling and energy storage analysis in Mn-modified lead free BiFeO3-BaTiO3 solid solutions.
- Source :
-
Journal of Applied Physics . 10/7/2019, Vol. 126 Issue 13, pN.PAG-N.PAG. 12p. 4 Charts, 11 Graphs. - Publication Year :
- 2019
-
Abstract
- The present study pertains to magnetoelectric coupling and energy storage analysis of (1 − x)BiFe0.95Mn0.05O3-xBaTiO3 (BFMO-BT) with x = 0.1, 0.2, 0.3 lead free solid solutions. BFMO-BT solid solutions possessed a cubic structure as confirmed from powder XRD and the Rietveld refinement. A maximum ferroelectric polarization of 0.82 μC/cm2 was observed in BFMO-0.3BT. BFMO-0.3BT exhibited a maximum energy storage density (WU) of 1.97 J/cm3 and an energy conversion efficiency of 81.7%. Enhanced bulk magnetization was associated with the lattice defects; however, it decreased with increased BT content. For BFMO-0.3BT, temperature dependent susceptibility, dielectric measurement, and differential scanning calorimetry measurement revealed the magnetic transition temperature to be 275 °C, 293 °C, and 223 °C, respectively. The linear magnetoelectric coupling coefficient was measured by quantifying change in maximum polarization with respect to the applied magnetic field and was found to be 28.55 mV cm−1 Oe for BFMO-0.3BT. Conductivity measurements of BFMO-0.3BT revealed a maximum value of activation energy, i.e., 0.21 eV at 1 kHz. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00218979
- Volume :
- 126
- Issue :
- 13
- Database :
- Academic Search Index
- Journal :
- Journal of Applied Physics
- Publication Type :
- Academic Journal
- Accession number :
- 139012147
- Full Text :
- https://doi.org/10.1063/1.5119291