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A Co8 metallacycle stabilized by double anion–π interactions.

Authors :
Alexandropoulos, Dimitris I.
Dolinar, Brian S.
Xie, Haomiao
Vignesh, Kuduva R.
Dunbar, Kim R.
Source :
Chemical Communications. 10/21/2019, Vol. 55 Issue 82, p12356-12359. 4p.
Publication Year :
2019

Abstract

Self-assembly reactions of CoII ions in the presence of the 2,2-bipyrimidine (bpym) ligand produced both a dinuclear and an octanuclear cation with the nuclearity being governed by hydrogen-bonding versus anion–π interactions between the anions and the ligands. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*ANIONS
*IONS
*CATIONS

Details

Language :
English
ISSN :
13597345
Volume :
55
Issue :
82
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
139054369
Full Text :
https://doi.org/10.1039/c9cc04151f