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cis-Dinitrito (1,4,8,11-tetraazacyclo-tetradecane-κ4N)chromium(III) nitrite.
- Source :
-
Acta Crystallographica: Section C (Wiley-Blackwell) . Jun2004, Vol. 60 Issue 6, pm238-m240. 3p. 3 Diagrams, 2 Charts. - Publication Year :
- 2004
-
Abstract
- In the title compound, [Cr(ONO)2(cyclam)]NO2 (cyclam is 1,4,8,11-tetraazacyclotetradecane, C10H24N2), the complex cation is located on a twofold symmetry axis. The central Cr atom has a distorted octahedral coordination, involving two Cr-O bonds, with the monodentate nitrite O atoms adopting a cis configuration, and four Cr-N bonds. The mean Cr-N and Cr-O distances are 2.0895 (14) and 1.9698 (14) Å. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CHROMIUM compounds
*INORGANIC compounds
*NITRITES
*CATIONS
*ATOMS
*CHEMICAL bonds
Subjects
Details
- Language :
- English
- ISSN :
- 01082701
- Volume :
- 60
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section C (Wiley-Blackwell)
- Publication Type :
- Academic Journal
- Accession number :
- 13919893
- Full Text :
- https://doi.org/10.1107/S0108270104007656