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Solid-state supramolecular architectures of a series of Hg(II) halide coordination compounds based on hydroxyl-substituted Schiff base ligands.
- Source :
-
CrystEngComm . 11/7/2019, Vol. 21 Issue 41, p6301-6312. 12p. - Publication Year :
- 2019
-
Abstract
- Crystal engineering of coordination complexes has become an important research domain of modern inorganic chemistry. Herein, six Hg(II) coordination compounds containing 2-((pyridin-3-ylmethylene)amino)phenol and 4-((pyridin-4-ylmethylene)amino)phenol ligands were synthesized and characterized by single crystal X-ray crystallography and spectroscopic techniques. The crystal structure of these coordination compounds was studied using geometrical and Hirshfeld analyses as well as theoretical calculations. The results revealed the contribution of π-stacking, as well as hydrogen bonding interactions in the supramolecular architecture of these coordination compounds. This study may provide further insight into elucidating the role of weak non-covalent interactions in the supramolecular assembly of metal-containing compounds. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 21
- Issue :
- 41
- Database :
- Academic Search Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 139233204
- Full Text :
- https://doi.org/10.1039/c9ce01078e