Investigation of structural and magnetic properties of multiferroic [formula omitted] Perovskites, prepared by citrate auto-combustion technique.

• La 1− x Y x FeO 3 had been synthesized by a combustion method using citric acid. • Structural and microstructural have been studied using XRD and Rietveld method. • The estimated values of crystallite size from HRTEM and XRD data were coincident. • LYFO crystals are canted antiferromagnets with room temperature weak ferromagnetism. • Magnetization versus temperature M(T) and M(H) hysteresis loop were analyzed. In this work, the structural and magnetic properties of multiferroic La 1 - x Y x FeO 3 perovskites, (x = 0.00, 0.05, 0.10, 0.15, 0.20, 0.25 and 0.30) synthesized through Sol-gel auto-combustion technique were investigated.The room temperature synchrotron X-ray diffraction (XRD) analysis revealed that the all the synthesized samples consisted of the polycrystalline orthorhombic structure perovskites (space group pnma), and tolerance factor confirmed the phase stability of the prepared perovskite system.The Williamson-Hall plots based on synchrotron XRD data were employed to estimate the average particle diameter and vary from 18.8 nm to 37.5 nm.For a deeper insight into the crystal structure, high-resolution transmission microscopy imaging (HRTEM) was performed.The estimated values of crystallite size from HRTEM and synchrotron XRD data were coincident.Many of crystallographic parameters and electron density measurements were calculated by Rietveld refinement of synchrotron XRD data. La 1 - x Y x FeO 3 perovskite crystals are canted antiferromagnets with a weak ferromagnetism at room temperature.Selected Area Electron Diffraction (SAED) patterns of the investigated samples exhibited spotty ring patterns, confirming the polycrystalline character.The magnetic properties were gotten through analyzing the magnetization versus temperature M(T) and M(H) hysteresis loop which characterized by a vibrating sample magnetometer (VSM). The orthoferrite La 1 - x Y x FeO 3 crystals are a promising candidate for optical device applications in broad temperature range and high power system. [ABSTRACT FROM AUTHOR]