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Direct Synthesis of Dihydropyrrolo[2,1‐a]Isoquinolines through FeCl3 Promoted Oxidative Aromatization.
- Source :
-
Advanced Synthesis & Catalysis . 10/22/2019, Vol. 361 Issue 20, p4772-4780. 9p. - Publication Year :
- 2019
-
Abstract
- We have developed a straightforward FeCl3 promoted synthesis of dihydropyrrolo[2,1‐a]isoquinolines through formal (3+2) cycloaddition/oxidative aromatization cascade of dihydroisoquinoline with Morita‐Baylis‐Hillman carbonates (up to 96% yield). Further modifications of the obtained products were successful through simple chemical transformations providing a diverse range of natural product‐like molecules (12 examples). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 361
- Issue :
- 20
- Database :
- Academic Search Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 139252667
- Full Text :
- https://doi.org/10.1002/adsc.201900756