The Effect of Oxygen and Argon Gas Flow Rate on OH Radical Production and Dye Decolorization by Pulsed Discharge in Spray Droplet Reactor.

Nonequilibrium plasma is an effective and one of versatile advanced oxidation process due to the formation of reactive species such as hydroxyl radicals, oxygen atom, and hydroperoxyl radicals. In pulsed discharge, free electrons gain energy from an imposed electric field and lose this energy through collisions with neutral gas/liquid molecules. The transfer of energy to the molecules leads to the formation of a variety of new species including atoms, free radicals, and ions. These products are all active chemically, and in our case, we measure the amount of hydroxyl radicals generated in the reactor and also the amount of escaped ozone generated in the reactor and decolorized indigo reagent in a graduated cylinder (GC). In this paper, we used oxygen and argon gases in various flow rate and mixed ratios to feed a gaseous phase in a water spraying droplet reactor. The experimental results indicated that the oxygen and O2/Ar mixture flow rates in spraying reactor have an effect on both hydroxyl radical generation and decolorization of indigo reagent solution. Argon gas discharge has less effect on hydroxyl radical production compared to the oxygen gas discharge with the same flow rates and no effect on the decolorization of indigo reagent solution in GC. We obtained remarkable results on both hydroxyl radical generation rate and decolorization efficiency of indigo reagent solution when we discharged with the mixture of O2/Ar “especially when the ratio has more oxygen than argon gas.” Hence, the presence of oxygen in the water spray plasma discharge is very important as it influence the generation of reactive species such as O atoms and ozone in the gas and liquid phase, which can react directly with organic contaminants and also contribute to more production of hydroxyl radicals in the aqueous phase. [ABSTRACT FROM AUTHOR]