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Synthesis, Characterization and Crystal Structures of Oxidovanadium(V) and Dioxidomolybdenum(VI) Complexes Derived from 2-bromo-N'-(2-hydroxy-3-methoxybenzylidene)benzohydrazide with Catalytic Property.
- Source :
-
Russian Journal of Coordination Chemistry . Nov2019, Vol. 45 Issue 11, p809-816. 8p. - Publication Year :
- 2019
-
Abstract
- A hydrazone compound 2-bromo-N'-(2-hydroxy-3-methoxybenzylidene)benzohydrazide (H2L) was prepared and characterized by IR, UV-Vis and NMR spectra. Based on the hydrazone compound, a new oxidovanadium(V) and a new dioxidomolybdenum(VI) complexes, [VO(L)(OEt)(EtOH)] (I) and [MoO2(L)(OH2)] (II), were prepared and characterized by IR, UV-Vis, NMR spectra, and single crystal X-ray diffraction (CIF files nos. 1866755 (I) and 1866756 (II)). Complex I crystallizes as the monoclinic space group P21/c with unit cell dimensions a = 12.8733(12), b = 13.5088(13), c = 11.9262(11) Å, β = 91.765(2)°, V = 2073.0(3) Å3, Z = 4, R1 = 0.0524, wR2 = 0.1329, GOOF = 1.245. Complex II crystallizes as the monoclinic space group P21/c with unit cell dimensions a = 8.1140(9), b = 16.2975(19), c = 13.4318(15) Å, β = 106.456(2)°, V = 1703.4(3) Å3, Z = 4, R1 = 0.0296, wR2 = 0.0728, GOOF = 1.046. X-ray analysis indicates that the complexes are mononuclear species with the metal atoms in octahedral coordination. The complexes were studied for catalytic oxidation property on some olefins with tert-butyl hydrogen peroxide as oxidant. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703284
- Volume :
- 45
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Russian Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 139458359
- Full Text :
- https://doi.org/10.1134/S1070328419110034