Ultrawideband Surface Enhanced Raman Scattering in Hybrid Graphene Fragmented‐Gold Substrates via Cold‐Etching.

Conventional surface enhanced Raman scattering (SERS) substrates are well known for their supreme electromagnetic enhancements and ultrahigh sensitivity in detecting molecules at low concentrations. However, large‐area quasi‐uniform SERS substrates are difficult to achieve by standard top‐down nanofabrication techniques, resulting in fluctuant SERS responses and unwanted fluorescence interferences, which severely limit their performances in practical applications. To tackle these challenges, a large‐scale quasi‐uniform hybrid graphene fragmented‐gold substrate with stable and reproducible SERS readouts as well as large enhancement factors over an ultrawideband spectrum is developed. The hybrid substrate is fabricated via cold‐etching through a controllable break up of a thin gold film followed by a graphene transfer. The stimulated localized surface plasmons interact strongly with the graphene layer, leading to spectrally and spatially modified graphene‐mediated surface enhanced Raman scattering (GSERS) responses. The perfect monolayer graphene of the GSERS substrate prevents adsorbates from the atmosphere and direct contact between bonded molecules and gold, thus reducing the catalytic activity of gold and producing clean, stable, and reproducible molecular Raman signals. The easy‐fabricated hybrid GSERS substrate not only provides a powerful platform to collect robust molecular Raman spectra but also shows great potentials for future mass production of high‐performance nanophotonic devices. [ABSTRACT FROM AUTHOR]