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Signatures of Through‐Space Charge Transfer in Two‐Photon Absorption of Paracyclophane Derivatives.
- Source :
-
Bulletin of the Korean Chemical Society . Nov2019, Vol. 40 Issue 11, p1076-1086. 11p. - Publication Year :
- 2019
-
Abstract
- Third order polarizability, (γ) taken from the collective electronic oscillator (CEO) method was used to calculate the two‐photon absorption (TPA) of tetrastyryl‐[2,2]paracyclophane derivatives with different through‐space charge transfer configurations considering various donor and acceptor combinations at the terminal styryl groups. For the virtually same linear absorption, different TPA spectra were obtained. For controlling and fine‐tuning frequency and cross‐sections of TPA the through‐space charge transfer interactions can be used. The results are explained by the electronic density matrices corresponding to governing oscillators in one‐ and two‐photon absorption and the ground state. It is indicated that for the studied systems mainly the lowest four oscillators are responsible for the TPA cross‐sections rather than a simple effective three‐state model. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02532964
- Volume :
- 40
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Bulletin of the Korean Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 139742618
- Full Text :
- https://doi.org/10.1002/bkcs.11874