Catalytic Decomposition of Oleic Acid to Fuels and Chemicals: Roles of Catalyst Acidity and Basicity on Product Distribution and Reaction Pathways.

The roles of catalyst acidity and basicity playing in catalytic conversion of oleic acid were studied in a fixed-bed micro-reactor at atmospheric pressure. The chemical compositions of the petroleum-like products were obtained and the reaction pathways of different catalysts are discussed. The metal oxides are suitable for upgrading oleic acid into organic liquid products (OLPs). Over 98% oxygen was removed when CaO, MgO, and TiO2 were implemented, whereas a minimum oxygen removal lower than 20% was obtained by using quartz. The oxygen removal was 73% by alumina; however, the light oil yield (to feed) and the valuable product yield received were the highest in all investigated catalysts. The hydrocarbons in OLPs, overwhelmingly presenting in the product, were found to be alkenes and cycloalkenes, followed by saturated hydrocarbons, and then aromatics lower than 4%. For Lewis acidic catalysts, higher acidity of the catalyst is beneficial to deoxygenation but also secondary cracking. CaO has higher dehydrogenation capability than MgO does. [ABSTRACT FROM AUTHOR]