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Accelerating water dissociation kinetics on Ni3S2 nanosheets by P-induced electronic modulation.
- Source :
-
Journal of Catalysis . Jan2020, Vol. 381, p493-500. 8p. - Publication Year :
- 2020
-
Abstract
- • P-doped Ni 3 S 2 nanosheet arrays were controlled preparation successfully. • The water dissociation kinetics of P-doped Ni 3 S 2 were tuned by electronic modulation. • The mechanism of HER performance improvement were revealed by DFT calculations. Developing efficient and low-cost electrocatalysts for hydrogen evolution reaction (HER) is important in clean energy systems. Non-noble transition metals are the most promising candidates for the replacement of conventional Pt group catalysts of HER. However, most non-noble metals show poor HER activity due to the intrinsic electronic structures. Herein, P atoms doped Ni 3 S 2 (P-doped Ni 3 S 2) nanosheets array grown on Ni foam has been successfully synthesized and further applied as the efficient electrocatalysts for HER in alkaline media. P-doped Ni 3 S 2 shows higher catalytic activity for HER compared with pristine Ni 3 S 2 , which affords the current densities of 10 mA cm−2 at an overpotential of 139 mV and long-term stability over 110 h. Density functional theory (DFT) calculations reveal that the introduction of P atoms modify the electronic structure of Ni 3 S 2 , enhance the electrical conductivity, optimize the HER Gibbs free-energy (Δ G H*) and the change of water adsorption energy (Δ G H2O*), and reduce the barrier of water dissociation optimize the HER Gibbs free-energy (Δ G H*), change water adsorption energy (Δ G H2O *) and reduce the barrier of water dissociation. Remarkably, energy integral of a crystal orbital Hamilton population (ICOHP) gives access to the contribution of an atom or a chemical bond to the distribution of one-particle bonding within the transistion state of water dissociation and reveals the reduced essence of water dissociation barrier. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00219517
- Volume :
- 381
- Database :
- Academic Search Index
- Journal :
- Journal of Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 140987737
- Full Text :
- https://doi.org/10.1016/j.jcat.2019.11.018