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Rational modulation of N, P co-doped carbon nanotubes encapsulating Co3Fe7 alloy as bifunctional oxygen electrocatalysts for Zinc–Air batteries.
- Source :
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Journal of Power Sources . Nov2019, Vol. 441, pN.PAG-N.PAG. 1p. - Publication Year :
- 2019
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Abstract
- Rational design and development of non-precious metal-based electrocatalysts for bifunctional oxygen reduction/evolution reactions (ORR/OER) are essential to realize the dischargeable Zinc-air batteries (ZABs). Herein, for the first time we synthesize CoFe-alloy nanoparticles enveloped by N, P co-doped carbon nanotubes (NPMC/CoFe), through a simple route by pyrolyzing dicyandiamide complex in the presence of phytic acid. The obtained electrocatalysts possess excellent ORR (a half wave potential of 0.896 V in 0.1 M KOH) and OER (η 10 mA cm-2 = 310 mV in 1 M KOH) performance, respectively. The liquid-state ZABs based on the NPMC/CoFe air-cathode demonstrates a high peak power density of 146.34 mW cm−2 and excellent durability. Specifically, flexible and button-like ZABs with impressive performances are both realized, which could power light-emitting diodes. This work offers an attractive approach to develop the nonprecious metal-based ORR/OER catalysts, and modulators for the design of performance oriented electrocatalysts for wider electrochemical energy applications. • NPMC/CoFe synthesized by pyrolyzing dicyandiamide-phytic acid complex. • The NPMC/CoFe exhibit ORR with E 1/2 of 0.896 V and OER with η 10 mA cm-2 of 310 mV. • The liquid ZABs showed a high peak power density of 146.34 mW cm−2. • The flexible and button-like rechargeable ZABs show the impressive performances. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03787753
- Volume :
- 441
- Database :
- Academic Search Index
- Journal :
- Journal of Power Sources
- Publication Type :
- Academic Journal
- Accession number :
- 141612833
- Full Text :
- https://doi.org/10.1016/j.jpowsour.2019.227177