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Enhanced catalytic performance of activated carbon-supported ru-based catalysts for acetylene hydrochlorination by azole ligands.
- Source :
-
Applied Catalysis A: General . Feb2020, Vol. 592, pN.PAG-N.PAG. 1p. - Publication Year :
- 2020
-
Abstract
- • The catalysts were prepared by coordinating the Ru precursor with azole ligands. • The Ru-L 8 /AC catalyst exhibited the superior performance to the other catalysts. • The coordination helps to stabilise high valence Ru and produce more active species. • The coordination contributes to the anchoring and dispersion of active species. • The interaction enhanced the adsorption ability for reactants. Supported Ru-L x /AC catalysts were synthesised by coordinating a Ru precursor with several azole ligands and assessed for acetylene hydrochlorination. The results demonstrated that the coordinated Ru-imidazole/AC (Ru-L 1 /AC) catalyst exhibited superior catalytic activity compared to that of catalysts coordinated with other ligands. In addition, the substitution of hydrogen on the imidazole ring by electron-donating substituents further improved the catalytic performance. Specifically, the coordination between the ruthenium precursor and heteroatom in the ligands, which contain a conjugated structure and an electron-donating substituent, promoted the transfer of electrons from the heteroatom to Ru cation and augmented the electron cloud density around the active centres, which helps stabilise high-valence Ru and produce more active Run+ species. In addition, the coordination contributed to the anchoring and dispersion of active species, which improved the catalytic hydrochlorination of acetylene. Thus, the as-designed Ru-1-isopropyl imidazole/AC (Ru-L 8 /AC) catalyst exhibits a superior performance and good application prospect. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0926860X
- Volume :
- 592
- Database :
- Academic Search Index
- Journal :
- Applied Catalysis A: General
- Publication Type :
- Academic Journal
- Accession number :
- 141630804
- Full Text :
- https://doi.org/10.1016/j.apcata.2020.117431