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Bifunctional separator with sandwich structure for high-performance lithium-sulfur batteries.
- Source :
-
Journal of Colloid & Interface Science . Feb2020, Vol. 559, p13-20. 8p. - Publication Year :
- 2020
-
Abstract
- The bifunctional separator modified by Al 2 O 3 and CNTs was successfully prepared by a facile method, The separator not only act as a physical barrier to prevent the diffusion of polysulfides, but also restrain the growth of lithium dendrites, It show excellent cycling stability (760.4 mA h g−1 at 0.2 C after 100 cycles) and promising rate performance. Severe "Shuttle effect" and uncontrollable lithium-dendrite growth are ongoing challenges that hinder the practical application of Lithium-sulfur (Li-S) batteries. Herein, a bifunctional separator was modified by Al 2 O 3 and carbon nanotubes (CNTs) via a facile method. Li-S battery assembled with the modified separator shows excellent cycling stability (760.4 mA h g−1 at 0.2 C after 100 cycles) and promising rate performance. The reason is ascribed to synergistic effect of CNTs and Al 2 O 3 double coating layers, the strong physicochemical interaction between Al 2 O 3 and the polysulfides could alleviate the shuttle effect, and the high conductivity of CNTs can facilitate the reaction kinetics of sulfur and its corresponding discharge products, respectively, which can improve the utilization ratio of sulfur. In addition, the double protection layers improve the hardness of the separator, as well as regulate Li+ ion deposition, which can effectively prevent the formation of lithium dendrites, thus the safety of the batteries are significant improved. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00219797
- Volume :
- 559
- Database :
- Academic Search Index
- Journal :
- Journal of Colloid & Interface Science
- Publication Type :
- Academic Journal
- Accession number :
- 141633421
- Full Text :
- https://doi.org/10.1016/j.jcis.2019.10.001