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Synthesis and Structural Characterization of a Cobalt Coordination Polymer with Formate and Bis(4-(1H-imidazol-1-yl)phenyl)methanone Ligands.
- Source :
-
Crystallography Reports . Dec2019, Vol. 64 Issue 7, p1071-1074. 4p. - Publication Year :
- 2019
-
Abstract
- A cobalt coordination polymer, {[Co(L1)2(H2O)2] · (HCOO)2 · H2O}n, where L1 is a bis(4-(1H-imidazol-1-yl)phenyl)methanone, has been synthesized and characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The crystal crystallizes in the triclinic sp. gr. with the unit cell parameters a = 7.9504(6), b = 10.0231(7), c = 13.3129(8) Å, and α = 88.399(5)°, β = 75.310(6)°, γ = 79.179(6)°, Z = 1. The Co2+ ion has a distorted octahedral environment with two O atoms from two water molecules and four N atoms from four L1 ligands. A thermal stability of polymer has been discussed. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10637745
- Volume :
- 64
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Crystallography Reports
- Publication Type :
- Academic Journal
- Accession number :
- 141916719
- Full Text :
- https://doi.org/10.1134/S1063774519070228