Interfacial synthesis of crystalline two-dimensional cyano-graphdiyne.

A well-defined crystalline cyano-functionalized graphdiyne (CN-GDY) is synthesized at a liquid/liquid interface through alkyne–alkyne coupling reactions. The configurations and nanostructures of CN-GDY were well characterized by TEM, SEM, AFM, XPS, and Raman spectroscopy. HR-TEM and selected area electron diffraction (SAED) in combination with structure simulation firmly revealed a 9-fold stacking mode for CN-GDY. [ABSTRACT FROM AUTHOR]