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Synthesis of Coordination Polymers from the Heterometallic Carboxylate Complexes with Chelating N-Donor Ligands.
- Source :
-
Russian Journal of Coordination Chemistry . Jan2020, Vol. 46 Issue 1, p1-14. 14p. - Publication Year :
- 2020
-
Abstract
- New trinuclear Cd–Ln molecular complexes [EuCd2(O2CC6F5)6(NO3)(Bipy)2] (I, Bipy is 2,2'-bipyridine) and [LnCd2(Bzo)6(NO3)(Phen)2] · 4MeCN (Ln = Tb (II), Eu (III), Bzo is anion of 3,5-di-tert-butylbenzoic acid, Phen is 1,10-phenanthroline) are studied. Their structures are determined by X-ray structure analysis (СIF files CCDC nos. 1938125 (I), 1938124 (II)) or by X-ray diffraction analysis (III), and the photoluminescence properties are studied. The reactions of complexes I and II with terephthalic acid (H2Bdc) are accompanied by the destruction of the heterometallic molecules to form 2D coordination polymers [Cd3(Bbdc)3(Bipy)2]3n · 4nMeCN · nH2O (IV) and [Cd2(Bdc)2(Phen)2]n · 2nDMF (V) (СIF files CCDC nos. 1938126 and 1937492, respectively). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703284
- Volume :
- 46
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Russian Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 142316359
- Full Text :
- https://doi.org/10.1134/S1070328420010078