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Electrochemically Enabled Intramolecular Aminooxygenation of Alkynes via Amidyl Radical Cyclization.
- Source :
-
Chinese Journal of Chemistry . Apr2020, Vol. 38 Issue 4, p394-398. 5p. - Publication Year :
- 2020
-
Abstract
- Summary of main observation and conclusion: An electrochemical synthesis of oxazol‐2‐ones and imidazol‐2‐ones has been developed via 5‐exo‐dig cyclization of propargylic carbamates‐ and ureas‐derived amidyl radicals. The electrosynthesis relies on the dual function of 2,2,6,6‐tetramethylpiperidin‐ 1‐yl)oxyl (TEMPO) as a redox mediator for amidyl radical formation and an oxygen atom donor. The reactions are conducted under mild conditions using a simple setup and provide convenient access to functionalized oxazol‐2‐ones and imidazol‐2‐ones from readily available materials. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKYNES
*REACTIVE oxygen species
*INTRAMOLECULAR catalysis
*ELECTROSYNTHESIS
Subjects
Details
- Language :
- English
- ISSN :
- 1001604X
- Volume :
- 38
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Chinese Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 142336818
- Full Text :
- https://doi.org/10.1002/cjoc.201900500