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Synthesis of diaryl ether components of ellagitannins using ortho-quinone with consonant mesomeric effects.
- Source :
-
Chemical Communications . 4/11/2020, Vol. 56 Issue 28, p3991-3994. 4p. - Publication Year :
- 2020
-
Abstract
- Methods for synthesizing C–O digallate structures, the basic unit of diaryl ether components of natural ellagitannins, are described. In the designed building block derived from gallic acid, consonantly overlapped mesomeric effects enhanced its electrophilicity. This building block demonstrated substantial reactivity to improve the synthesis of dehydrodigalloyl, tergalloyl, and valoneoyl groups. [ABSTRACT FROM AUTHOR]
- Subjects :
- *RESONANCE effect
*ETHER synthesis
*GALLIC acid
*ELLAGITANNINS
*QUINONE
*ETHERS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 28
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 142616055
- Full Text :
- https://doi.org/10.1039/d0cc00889c