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Toward Pluramycins with Epoxy Side Chain: Syntheses of Kidamycinone and Epoxykidamycinone (Saptomycinone H).
- Source :
-
Chemistry - An Asian Journal . 3/16/2020, Vol. 15 Issue 6, p828-832. 5p. - Publication Year :
- 2020
-
Abstract
- For exploring general routes to the pluramycinclass of antibiotics, including congeners with epoxide-bearing side chains, syntheses of kidamycinone and its epoxide (epoxykidamycinone) have been achieved. At the stage of the A-ring cyclization with alkene-bearing side chain, the desired 6-endo product was obtained as a major compound, although the corresponding undesired 5-exo product was also formed. [ABSTRACT FROM AUTHOR]
- Subjects :
- *NATURAL products
*ANTIBIOTICS
Subjects
Details
- Language :
- English
- ISSN :
- 18614728
- Volume :
- 15
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Chemistry - An Asian Journal
- Publication Type :
- Academic Journal
- Accession number :
- 142838143
- Full Text :
- https://doi.org/10.1002/asia.201901807