Acridine orange as a coreactant for efficient electrogenerated chemiluminescence of tris(2,2′-bipyridine)ruthenium(II) and its use in selective and sensitive detection of thiourea.

A new and efficient anodic Ru(bpy)32+ ECL system by using acridine orange (3,6-Bis(dimethylamino)acridine, AO) as a coreactant was reported in a neutral medium. The developed Ru(bpy)32+–AO system displayed a higher ECL intensity than that of the classic Ru(bpy)32+– oxalate ECL system, and was further exploited for the ECL detection of thiourea for the first time. [ABSTRACT FROM AUTHOR]