Back to Search
Start Over
1,2-Diaza-4-phospholide complexes of chromium(II): dipotassium organochromates behaving as single-molecule magnets.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 6/7/2020, Vol. 49 Issue 21, p6945-6949. 5p. - Publication Year :
- 2020
-
Abstract
- The 1,2-diaza-4-phospholide (dp−) dipotassium ate complexes of chromium(II) {[(η1-N-3,5-tBu2dp)4Cr][(η5-(N,N,C,C,P))2-K(η1-O-THF)2]2} (5) and {[(η1-N-3,5-Ph2dp)4Cr][(η5-(N,N,C,C,P))2-K(η1-O-THF)2]2}∞ (6) were synthesized and characterized by X-ray single crystal structure analysis. Complex 5 with a near-square planar geometry at the chromium(II) ion was unambiguously characterized by the high field electron paramagnetic resonance (HF-EPR) technique and magnetic measurements, revealing that it is a field-induced single-molecule magnet (SMM). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 49
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 143550851
- Full Text :
- https://doi.org/10.1039/d0dt00878h