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The intermolecular interactions of methanol, pyrrole and chloroform in a binary solvent.
- Source :
-
Thermochimica Acta . Jul2020, Vol. 689, pN.PAG-N.PAG. 1p. - Publication Year :
- 2020
-
Abstract
- • Solution enthalpies proton donors in binary solvents were measured. • The approach to evaluate the intermolecular interactions contributions of solute in binary solvent has been demonstrated. • The enthalpies of specific interaction of solute in binary solvent were calculated. The work focuses on a thermochemical study of solvation of organic non-electrolytes in various binary mixed solvents. The enthalpies of solution of pyrrole, methanol and chloroform in carbon tetrachloride – pyridine binary mixture were measured at 298.15 K. Data on solution enthalpies of solute – binary solvent for more than 350 systems has been collected. The specific and non-specific terms to the enthalpies of solvation of proton donors have been evaluated for the first time for the mixed solvent using the model previously adapted for individual solvents. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00406031
- Volume :
- 689
- Database :
- Academic Search Index
- Journal :
- Thermochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 143701513
- Full Text :
- https://doi.org/10.1016/j.tca.2020.178640