Novel talc encapsulated lanthanum alginate hydrogel for efficient phosphate adsorption and fixation.

In the present work, talc (a low-cost clay) encapsulated salts alginate (TAL) beads were synthesized by cross-linking with lanthanum ion and tested for phosphate adsorption. Multiple methods were applied for the characterization of composites. The combined effect of talc and lanthanum improved phosphate removal performance of TAL beads. Factors such as talc content, La3+ concentration, adsorbent dosage, pH, co-existing ions (Cl−, NO 3 − and SO 4 2−) were studied in batch experiments. The optimized TAL-7 beads exhibited satisfactory selectivity towards phosphate in the coexistence of competing anions and could remain efficient phosphate removal in the pH range of 4–6. The phosphate removal efficiency reached to 95% with a maximum uptake of 16.4 mg P/g obtained at the optimal pH 4. Further experiments suggested that Langmuir isotherm model and the pseudo-second-order kinetic model could well describe the phosphate adsorption process of TAL-7 beads. Moreover, TAL-7 beads exhibited superior phosphate fixation performance in the long-term experiment. The results from adsorption experiment and characterization analysis demonstrated that TAL-7 beads could be a cost-effective and promising biosorbent for phosphate adsorption and fixation in the aqueous environment. Image 1 • The talc/alginate/lanthanum (TAL) beads were firstly synthesized and characterized. • Enhanced removal and selective sorption of phosphate were obtained by optimized TAL. • This novel adsorbent exhibited satisfactory phosphate fixation performance. • Electrostatic interaction and ligand exchange were the main adsorption mechanisms. [ABSTRACT FROM AUTHOR]