Molecular investigation into the transformation of dissolved organic matter in mature landfill leachate during treatment in a combined membrane bioreactor-reverse osmosis process.

• A combined process to treated landfill leachate was studied at the molecular level. • Mature landfill leachate contained a variety of organics with low bioavailability. • A membrane bioreactor can remove some organics from mature landfill leachate. • A reverse osmosis system can almost completely remove organics from mature leachate. This study investigated the effectiveness of a combined membrane bioreactor (MBR) and reverse osmosis (RO) process for treating leachate produced by a large-scale anaerobic landfill. The MBR process had limited treatment efficiency for removing organic pollutants, but when combined with RO, the integrated system completely removed macromolecular compounds (i.e., humic- and fulvic-like substances) and produced effluent that satisfied the applicable discharge standard. The landfill leachate contained many types of DOM that had high molecular weight and were highly unsaturated. Although the MBR process removed some DOM that had a relatively low saturated degree (mainly aliphatic compounds (2.0 ≥ H/C ≥ 1.5) with relatively high bioavailability), many bio-refractory compounds were not removed. The RO system greatly reduced the content of residual DOM in MBR effluent and was effective for removing heteroatom DOM, especially polycyclic aromatics (AI > 0.66) and polyphenols (0.66 ≥ AI > 0.50). The effluent from the combined process of MBR and RO treatment mainly contained a small number of aliphatic compounds and phenolic compounds (AI ≤ 0.50 and H/C < 1.5) that had higher bioavailability than DOM in the raw leachate and posed little environmental risk. [ABSTRACT FROM AUTHOR]