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Palladium/Copper‐Mediated Switchable Approaches towards (Chloro)ethenylphosphorylamides by Phosphorylamides and Alkenes.
- Source :
-
European Journal of Organic Chemistry . 6/30/2020, Vol. 2020 Issue 24, p3576-3590. 15p. - Publication Year :
- 2020
-
Abstract
- A switchable access to ethenylphosphorylamides and chloroethenylphosphorylamides from phosphorylamides and alkenes has been disclosed herein. With the assistance of Pd(OAc)2, a catalytic loading of CuCl2 or CuBr (20 mol‐%) led to the occurrence of dehydrogenative cross coupling reactions with high efficiency and broad substrate scope, while 1.0 equivalent of CuCl2 rendered the dehydrogenative amidochlorination reactions to take place with high stereoselectivity. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKENES
*STEREOSELECTIVE reactions
*PALLADIUM
Subjects
Details
- Language :
- English
- ISSN :
- 1434193X
- Volume :
- 2020
- Issue :
- 24
- Database :
- Academic Search Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 144313473
- Full Text :
- https://doi.org/10.1002/ejoc.202000258