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Gold(I) complexes bearing P‐pyrrole phosphine ligands: Synthesis and catalytic activity towards cycloisomerization of 1,6‐enynes.
- Source :
-
Applied Organometallic Chemistry . Aug2020, Vol. 34 Issue 8, p1-9. 9p. - Publication Year :
- 2020
-
Abstract
- P‐pyrrole phosphines (R2Ppyr), in which a pyrrole group is directly bonded to the phosphorus atom, act as monodentate k‐P ligands towards gold(I) center to afford either neutral or cationic mononuclear complexes as well as neutral dinuclear complexes. All of these new gold(I) complexes have been structurally characterized and their first uses in catalysis have demonstrated their effectiveness as precatalysts for the enyne cycloisomerization reactions. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CYCLOISOMERIZATION
*CATALYTIC activity
*PYRROLE derivatives
*CATALYSIS
*PHOSPHINES
Subjects
Details
- Language :
- English
- ISSN :
- 02682605
- Volume :
- 34
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Applied Organometallic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 144472802
- Full Text :
- https://doi.org/10.1002/aoc.5709