Back to Search
Start Over
Selective oxygenation of unactivated C–H bonds by dioxygen via the autocatalytic formation of oxoiron(V) species.
- Source :
-
Chemical Communications . 8/4/2020, Vol. 56 Issue 60, p8484-8487. 4p. - Publication Year :
- 2020
-
Abstract
- Selective catalytic oxygenation of unactivated C–H bonds for a series of substrates by dioxygen using iron complexes was performed without the use of a co-reductant. Mechanistic studies indicate that the reaction proceeded via the autocatalytic formation of an oxoiron(V) intermediate, which brings high regioselectivity and stereoretention. [ABSTRACT FROM AUTHOR]
- Subjects :
- *AUTOCATALYSIS
*OXYGENATION (Chemistry)
*SPECIES
*VANADIUM
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 60
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 144806295
- Full Text :
- https://doi.org/10.1039/d0cc03071f