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New Metal−Organic Framework with Uninodal 4-Connected Topology Displaying Interpenetration, Self-Catenation, and Second-Order Nonlinear Optical Response.
- Source :
-
Crystal Growth & Design . Apr2010, Vol. 10 Issue 4, p1489-1491. 3p. - Publication Year :
- 2010
-
Abstract
- An interesting coordination complex based on a designed X ligand has been prepared. It displays a novel 4-connected uninodal net with point symbol (42·63·8) and vertex symbol [4.6.4.6.6.1012] which has never been observed in metal−organic frameworks/coordination polymers. Meanwhile, the compound displays intriguing structural features of interpenetration and self-catenation, as well as nonlinear optical properties. An interesting coordination complex based on a designed X ligand has been prepared. It displays a novel 4-connected uninodal net with point symbol (42·63·8) and vertex symbol [4.6.4.6.6.1012] which has never been observed in metal−organic frameworks/coordination polymers. Meanwhile, the compound displays intriguing structural features of interpenetration and self-catenation, as well as nonlinear optical properties. [ABSTRACT FROM AUTHOR]
- Subjects :
- *METAL-organic frameworks
*COORDINATION polymers
*LIGANDS (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 15287483
- Volume :
- 10
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Crystal Growth & Design
- Publication Type :
- Academic Journal
- Accession number :
- 144987781
- Full Text :
- https://doi.org/10.1021/cg100174h