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High-Resolution Ion-Imaging Studies of the Photodissociation of the BrCl+ Cation †.
- Source :
-
Journal of Physical Chemistry A . 9/30/2004, Vol. 108 Issue 39, p8077-8083. 7p. - Publication Year :
- 2004
-
Abstract
- The photofragmentation of state-selected BrCl+ cations has been investigated by velocity-map ion-imaging methods. Detailed analyses of the 79Br+ fragment velocities lead to the most precise values yet reported for (i) the spin−orbit coupling constant for the X2Π state, A = −2070 ± 4 cm-1; (ii) the bond dissociation energies of both states of 79Br35Cl+, 25019 ± 4 cm-1 (X2Π3/2) and 22949 ± 2 cm-1 (X2Π1/2); and (iii) the adiabatic ionization thresholds for forming 79Br35Cl+ parent ions in their X2Π3/2 and X2Π1/2 states, 88292 ± 6 and 90362 ± 4 cm-1, respectively. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10895639
- Volume :
- 108
- Issue :
- 39
- Database :
- Academic Search Index
- Journal :
- Journal of Physical Chemistry A
- Publication Type :
- Academic Journal
- Accession number :
- 145094481
- Full Text :
- https://doi.org/10.1021/jp049238q