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Structural Aspects of Long-Lived C7H82+ Dications Generated by the Electron Ionization of Toluene †.
- Source :
-
Journal of Physical Chemistry A . 3/9/2006, Vol. 110 Issue 9, p2970-2978. 9p. - Publication Year :
- 2006
-
Abstract
- The structure of the C7H82+ dication generated upon electron ionization of toluene is investigated by experimental and theoretical means. For the long-lived C7H82+ dication, the experimental findings obtained with a novel SIFT/GIB instrument suggest complete loss of structural integrity corresponding to the toluene structure. Instead, the manifold of C7H82+ dications most likely to be formed is assigned to a mixture of the cycloheptatriene dication and ring-protonated benzylium ions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10895639
- Volume :
- 110
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Journal of Physical Chemistry A
- Publication Type :
- Academic Journal
- Accession number :
- 145094685
- Full Text :
- https://doi.org/10.1021/jp0545288