Back to Search
Start Over
Using the Secondary PH/BH Functional Groups of an Active Geminal Frustrated Lewis Pair for Carbon Monoxide Reduction and Reactions with Nitriles and Isonitriles.
- Source :
-
Angewandte Chemie International Edition . 7/20/2020, Vol. 59 Issue 30, p12477-12483. 7p. - Publication Year :
- 2020
-
Abstract
- Reaction of the secondary alkynyl(Mes*)PH phosphane 2 with (Fmes)BH2⋅SMe2 gives the geminal PH/BH frustrated Lewis pair (FLP) 3. The PH and the BH functions are jointly used in the reduction of carbon monoxide under mild reaction conditions to give the [P]‐CH2‐O‐[B] product. A subsequent cycloaddition sequence results in the liberation of formaldehyde. The FLP 3 reacts with benzonitrile to give a P‐benzamidine, and it couples two isonitriles at the FLP framework. [ABSTRACT FROM AUTHOR]
- Subjects :
- *LEWIS pairs (Chemistry)
*CARBON monoxide
*ISOCYANIDES
*FUNCTIONAL groups
*NITRILES
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 59
- Issue :
- 30
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 145175869
- Full Text :
- https://doi.org/10.1002/anie.202000612