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Construction of durable flame-retardant and robust superhydrophobic coatings on cotton fabrics for water-oil separation application.
- Source :
-
Chemical Engineering Journal . Oct2020, Vol. 398, pN.PAG-N.PAG. 1p. - Publication Year :
- 2020
-
Abstract
- • Flame-retardant and superhydrophobic coatings were constructed on cotton fabrics by a facile two-step method. • The treated cotton showed super flame retardancy in terms of self-extinguishing behavior. • The peak heat release rate of the treated cotton was significantly reduced by 70% compared to pure cotton. • The treated cotton exhibited fascinating anti-fouling and water-oil separation abilities. • The coatings on cotton fabrics displayed good abrasion resistance and washing durability. A flame-retardant and superhydrophobic coating was deposited on cotton fabrics using a simple two-step spraying method. In detailed, the first step involved flame-retardant layer consisted of alkylammonium functional silsesquioxane (A-POSS)/phytic acid (PA) complex, while the second step generated superhydrophobic layer that was composed of hierarchical structured titanium oxide@polydimethylsiloxane (TiO 2 @PDMS) composite. The influence of the components' loading in the coating on flame-retardant, thermal and wetting properties of the coated cotton fabrics was investigated systematically. The optimized coated cotton sample denoted as C3-PDMS-TiO 2 was screened through limiting oxygen index (LOI), UL-94 flammability test, cone calorimetry measurement and water contact angle (WCA). Specifically, C3-PDMS-TiO 2 sample showed self-extinguishing behavior in the vertical burning test, as well as a significantly enhanced LOI to 29% from 18% for pristine cotton fabrics. Furthermore, the peak heat release rate (PHRR) and the total heat release (THR) values of C3-PDMS-TiO 2 were significantly declined by 70% and 41%, respectively, compared to those of pristine cotton fabrics. Additionally, C3-PDMS-TiO 2 exhibited super self-cleaning ability as a consequence of its superhydrophobic surface. Furthermore, C3-PDMS-TiO 2 was applied for water-oil separation, and exhibited robust ability even in strong acid- or alkali-oil mixtures. The C3-PDMS-TiO 2 fabrics also displayed super abrasion resistance (WCA > 139° after 50 abrasion cycles) and washing durability (self-extinguishing after 5 laundering cycles). This facile finishing technique has great potentials in application as multifunctional advanced textiles. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13858947
- Volume :
- 398
- Database :
- Academic Search Index
- Journal :
- Chemical Engineering Journal
- Publication Type :
- Academic Journal
- Accession number :
- 145205006
- Full Text :
- https://doi.org/10.1016/j.cej.2020.125661