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Diboration of 3-substituted propargylic alcohols using a bimetallic catalyst system: access to (Z)-allyl, vinyldiboronates.

Authors :
Peck, Cheryl L.
Nekvinda, Jan
Santos, Webster L.
Source :
Chemical Communications. 9/14/2020, Vol. 56 Issue 71, p10313-10316. 4p.
Publication Year :
2020

Abstract

The diboration of substituted propargylic alcohols has been achieved using a bimetallic Pd/Cu catalyst system. The in situ formation of a pentrafluoroboronic acid intermediate sufficiently activates the C–O bond towards dual catalysis affording (Z)-allyl, vinyldiboronates stereoselectively. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
56
Issue :
71
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
145476558
Full Text :
https://doi.org/10.1039/d0cc03563g