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Remarkable enhancement in hybrid improper ferroelectricity of Ca3Ti2O7 ceramics by a simple sol-gel process.
- Source :
-
Materials Letters . Nov2020, Vol. 278, pN.PAG-N.PAG. 1p. - Publication Year :
- 2020
-
Abstract
- • Ca 3 Ti 2 O 7 ceramics were successfully synthesized by a simple tartaric acid sol-gel method. • The remarkably enhanced remnant polarization (4.32 μC/cm2) was achieved. • The sample has the larger antiferroelectric distortion displacements and the larger grain. Ca 3 Ti 2 O 7 with Ruddlesden-Popper structure is a typical hybrid improper ferroelectric with large polarization. But the room-temperature ferroelectricity of Ca 3 Ti 2 O 7 ceramics prepared by a solid-state method is not good enough. In this work, Ca 3 Ti 2 O 7 ceramics with remarkably enhanced hybrid improper ferroelectricity have been successfully fabricated by a simple tartaric acid sol-gel method. The ceramic sample exhibits the highest remnant polarization (4.32 μC/cm2) to our knowledge and lower coercive electric field (108.7 kV/cm) at room temperature. The enhanced ferroelectricity of Ca 3 Ti 2 O 7 ceramics results from the larger antiferroelectric distortion displacements and the larger grain with irregular polygon features. These findings are beneficial for developing room-temperature single phase multiferroic materials with strong magnetoelectric coupling and excellent ferroelectricity. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0167577X
- Volume :
- 278
- Database :
- Academic Search Index
- Journal :
- Materials Letters
- Publication Type :
- Academic Journal
- Accession number :
- 145651226
- Full Text :
- https://doi.org/10.1016/j.matlet.2020.128447