A novel method for the synchronous absorption of SO2 and NO from marine diesel engines.

A novel method based on a Na 2 S 2 O 8 /urea composite system was used to both synchronously absorb SO 2 and NO from marine diesel engine emissions and reduce the nitrate residues in cleaning wastewater. In the Na 2 S 2 O 8 /urea solution, a temperature of over 60 °C and a Na 2 S 2 O 8 concentration of >0.05 mol/L were found to fully absorb SO 2 by overcoming the SO 2 release and effectively absorb NO. Urea successfully reduced the residual nitrate concentration and improves NO absorption at a concentration below 2 mol/L. The NO and SO 2 removal efficiencies reached 97.8 ± 1.5% and 100%, respectively, at 70 °C in 0.1 mol/L Na 2 S 2 O 8 and 1.5 mol/L urea solutions. The residual nitrate concentration was 8.12 ± 0.25 mg/L, far below the regulatory limit of 60 mg/L. Acidic conditions (pH ≤ 5.5) could be conducive to absorbing NO and reducing the residual nitrate concentration. Based on the experimental results, this novel method is highly promising for reducing ship emissions. • Marine NO and SO 2 removal efficiencies reached 100% in Na 2 S 2 O 8 solution. • Urea enhanced NO absorption and inhibited the formation of nitrate residue. • NO and SO 2 removal efficiencies of 97.8 ± 1.5% and 100%, respectively, were found. • Different redox processes coexisted in reducing ship emissions in Na 2 S 2 O 8 /urea. • Acidic conditions (pH ≤ 5.5) were favorable for NO absorption and nitrate inhibition. [ABSTRACT FROM AUTHOR]