Visible Light Driven Copper(I) Catalyzed Oxyamination of Electron Deficient Alkenes†.

Summary of main observation and conclusion: A visible light driven Cu(I)‐catalyzed intermolecular oxyamination of electron‐deficient olefins has been achieved by using O‐benzoylhydroxylamines as donors both for amine and oxygen. The transformation properties afford mild conditions and a wide substrate scope, providing access to ester derivatives of β‐amino alcohols with good yields and high regioselectivity. [ABSTRACT FROM AUTHOR]