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Air-stable Pd(0) catalyst bearing dual phosphine ligands: a detailed evaluation of air stability and catalytic property in cross-coupling reactions.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 9/28/2020, Vol. 49 Issue 36, p12814-12819. 6p. - Publication Year :
- 2020
-
Abstract
- We have synthesised an air-stable Pd(0) catalyst bearing donor and acceptor phosphine ligands (Complex 1). This study revealed the long-term air stability and catalytic property of Complex 1 as a catalyst for cross-coupling reactions, where it was stable in air for eight months. DFT calculations revealed that the acceptor ligands in Complex 1 decreased the HOMO energy level, which provided the observed air stability. Complex 1 successfully served as a catalyst for direct C–H arylation reactions and Suzuki–Miyaura cross-coupling reactions, and catalysed the reaction of a relatively inactive substrate, 2-chrolopyridine, which could not be achieved by conventional, air-stable Pd(0) catalysts. Isolating the intermediates of the coupling reactions revealed that each intermediate possessed the donor ligand (PCy3), which was determined to be responsible for imparting the high catalytic activity exhibited by Complex 1. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CATALYSTS
*LIGANDS (Chemistry)
*CATALYTIC activity
*PHOSPHINES
*AIR
*ARYLATION
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 49
- Issue :
- 36
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 146012903
- Full Text :
- https://doi.org/10.1039/d0dt02744h