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Undirected ortho-selectivity in C–H borylation of arenes catalyzed by NHC platinum(0) complexes.
- Source :
-
Mendeleev Communications . Sep2020, Vol. 30 Issue 5, p569-571. 3p. - Publication Year :
- 2020
-
Abstract
- Borylation of arenes with bis(pinacolato)diboron catalyzed by sterically encumbered NHC platinum complexes proceeds predominantly at ortho -position even in the absence of a directing group (o : m : p ratio up to 10: 3: 1). The similar borylation with pinacolborane would proceed less selectively. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09599436
- Volume :
- 30
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Mendeleev Communications
- Publication Type :
- Academic Journal
- Accession number :
- 146249991
- Full Text :
- https://doi.org/10.1016/j.mencom.2020.09.005