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Three novel Cd(II) dithiocarbamate complexes: synthesis, structural diversity and fluorescence properties.
- Source :
-
Journal of the Iranian Chemical Society . Nov2020, Vol. 17 Issue 11, p2867-2876. 10p. - Publication Year :
- 2020
-
Abstract
- Three new homoleptic cadmium (II) dithiocarbamate complexes having molecular formula [Cd(KL)2], (KL1 = C15H13N1F1S2) (1); (L2 = C13H11N1F1S2) (2); (L3 = C11H14N1O1S2) (3), have been synthesized and characterized by elemental analysis, spectroscopy (IR, 1H and 13CNMR and UV–Vis). Single crystal X-ray studies confirm that the complex 1 crystallises in Orthorhombic with space group Pna21 and holding dimeric structure. In this complex Cd2+ having distorted octahedral geometry about the metal centre forms 1D coordination polymeric structures. The dimeric form of complex 2 and 3 crystallizes in triclinic crystal lattice with space group P-1. [ABSTRACT FROM AUTHOR]
- Subjects :
- *FLUORESCENCE
*CHEMICAL formulas
*CRYSTAL lattices
*SPACE groups
*METALWORK
Subjects
Details
- Language :
- English
- ISSN :
- 1735207X
- Volume :
- 17
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Journal of the Iranian Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 146250696
- Full Text :
- https://doi.org/10.1007/s13738-020-01965-4