Detection of cadmium ions Byg-C3N4 functionalization on AlGaN/GaN high electron mobility transistor.

In this study, a novel, highly sensitive AlGaN/ GaN high electron mobility transistor (HEMT) sensor is demonstrated for the detection of cadmium ions by the functionalization of graphitic carbon nitride (g-C3N4). The preparation of g-C3N4 was done using the pyrolysis process of urea. The prepared g-C3N4 was functionalized on Au gated AlGaN/ GaN HEMT and the sensing performance was observed by the measurement of electrical characteristics of the device. The sensitivity and limit of detection of the modified g-C3N4 based AlGaN/ GaN HEMT sensor was observed as 0.2606 µA/ppb and 0.533 ppb respectively. The observed limit of detection is very low than the standard guideline values of World Health Organization (WHO) for drinking water. Furthermore, using AlGaN/GaN HEMT theory, we show that the sensing response is very fast due to the availability of 2-D electron gas (2DEG) and very sensitive due to the change in gate potential. The mechanism suggests that the decrement in the drain current was due to the reduction of Cd2+ ions on the g-C3N4 surface which generates negative redox potential at the gate terminal while exposing the functionalized HEMT to Cd2+ ions. Hence, a simple, miniaturized, sensitive and real-time sensor has been developed using AlGaN/GaN HEMT functionalized by g-C3N4 to detect Cd2+ ions in an aqueous environment. [ABSTRACT FROM AUTHOR]