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Multiphase phosphide cocatalyst for boosting efficient photocatalytic H2 production and enhancing the stability.
- Source :
-
Ceramics International . Jan2021, Vol. 47 Issue 1, p1414-1420. 7p. - Publication Year :
- 2021
-
Abstract
- Constructing appropriate cocatalysts to modify semiconductors is significant for improving photocatalytic H 2 production and stability. Transition metal phosphides (TMPs) with low-cost and high efficiency have been considered as one of the most promising non-noble-metal cocatalysts. Herein, a novel multiphase phosphide nanosheet, Fe 2 P/Ni 3 P cocatalyst, was target designed and in-situ incorporated with Cu 2 O nanocubes via a phosphorization method for photocatalytic H2 evolution under visible light irradiation. The optimal Cu 2 O/Fe 2 P/Ni 3 P sample provided 10-folds higher photocatalytic activity of H2 evolution rate (108.68 μmol g−1 h−1) than that of single Cu 2 O (18.6 μmol g−1 h−1), which could be ascribed to fast charge transfer from the Cu 2 O to multiphase phosphide Fe 2 P/Ni 3 P cocatalyst and efficient separation of the light-induced charge carriers. Moreover, the Fe 2 P/Ni 3 P cocatalyst also improved the photo-corrosion of Cu 2 O caused by the disproportionation reaction, leading the Cu 2 O/Fe 2 P/Ni 3 P hybrid possessed robust stability. Additionally, this work guarantees useful insights in employing novel TMPs-based cocatalysts to construct visible-light-responsive photocatalysts, which manifests promising applications in the dwindling supply of energy. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 47
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 146998411
- Full Text :
- https://doi.org/10.1016/j.ceramint.2020.08.265