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Porous Ni-Mo bimetallic hybrid electrocatalyst by intermolecular forces in precursors for enhanced hydrogen generation.
- Source :
-
Chemical Engineering Journal . Feb2021, Vol. 405, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
-
Abstract
- A low-cost porous bimetallic hybrid electrocatalyst (Ni/Mo 6 Ni 6 C@C nanoparticle) has been synthesized via a soft-template using Polyethylenimine (PEI), Polyoxometalate (POM) and metal ion as precursors. • The bimetallic catalysts Ni/Mo 6 Ni 6 C@C were synthesized by a soft-template method. • The intermolecular forces in precursors are the basis of forming Ni/Mo 6 Ni 6 C@C. • Ni/Mo 6 Ni 6 C@C exhibited excellent catalytic activity and durability for HER. • DFT calculations pinpoint the origin of the excellent performance of Ni/Mo 6 Ni 6 C@C. Hydrogen generated by water splitting devices is a promising way to solve energy issues, which is limited by Pt-based precious catalysts. Developing efficient Pt-free electrocatalyst for hydrogen evolution reaction (HER) is highly essential for the practical applications. Herein, we report a soft-template method to fabricate an efficient porous bimetallic hybrid material, dubbed Ni/Mo 6 Ni 6 C@C. Benefiting from the bimetallic feature and porous structure, Ni/Mo 6 Ni 6 C@C exhibits low overpotentials of 101 and 122 mV at 10 mA cm−2 with robust stability in alkaline and acidic media, respectively. Theoretical calculations demonstrate that the C sites of the Mo 6 Ni 6 C possess the most excellent electrocatalytic activity due to its Gibbs free energy of hydrogen adsorption closer to 0 eV. Moreover, the superior stability, metallic character and mechanical property are characterized by first-principles calculations, which are advantageous for the Mo 6 Ni 6 C to be the HER catalyst. This study supplies a concise strategy to prepare the highly efficient bimetallic electrocatalyst for HER. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13858947
- Volume :
- 405
- Database :
- Academic Search Index
- Journal :
- Chemical Engineering Journal
- Publication Type :
- Academic Journal
- Accession number :
- 147020804
- Full Text :
- https://doi.org/10.1016/j.cej.2020.126962