Bi4O(I3O10)(IO3)3(SeO4): trimeric condensation of IO43− monomers into the I3O105− polymeric anion observed in a three-component mixed-anion NLO material

Authors :: Mao, Fei-Fei
Hu, Jin-Yu
Li, Bing-Xuan
Wu, Hua
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 11/28/2020, Vol. 49 Issue 44, p15597-15601. 5p.
Publication Year :: 2020
Abstract: A novel mixed-anion NLO crystal, namely, Bi4O(I3O10)(IO3)3(SeO4), containing a brand-new "pinwheel-like" I3O105− polyiodate anion group was constructed from the trimeric condensation of IO43− monomers. Bi4O(I3O10)(IO3)3(SeO4) exhibits a complex 3D topological structure and gives a moderate second harmonic generation (SHG) signal about 1.1 times that of KH2PO4 (KDP). [ABSTRACT FROM AUTHOR]

Subjects :: *SECOND harmonic generation
*CONDENSATION
*MONOMERS
*ANIONS
*POLYMERIC nanocomposites

Language :: English
ISSN :: 14779226
Volume :: 49
Issue :: 44
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 147040015
Full Text :: https://doi.org/10.1039/d0dt03399e

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