Back to Search
Start Over
Single-crystal-to-single-crystal transformation and proton conductivity of three hydrogen-bonded organic frameworks.
- Source :
-
Chemical Communications . 12/25/2020, Vol. 56 Issue 99, p15529-15532. 4p. - Publication Year :
- 2020
-
Abstract
- We report the cyclic single-crystal-to-single-crystal transformation of three hydrogen-bonded organic frameworks (HOFs), induced by the change of temperature and humidity, which clearly reveals that the –SO3−and –NH2 groups in UPC-H7 and UPC-H8 facilitate the diffusion of water molecules into their anhydrous structures to form hydrous UPC-H9. Their proton conductivity was studied under different humidity at varying temperature, showing that the proton conductivity is closely related to water molecules entering the crystal structures arising from the hydrogen bonded reorganization in combination with the triaxial single-crystal proton conductivity tests. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 99
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 147729992
- Full Text :
- https://doi.org/10.1039/d0cc05402j